Publications

Rice, D. B.; Wijeratne, G. B.; Jackson, T. A., Mn K-edge X-ray absorption studies of mononuclear Mn(III)-hydroxo complexes. J Biol Inorg Chem 2017, 22 (8), 1281-1293.
Rice, D. B.; Massie, A. A.; Jackson, T. A., Manganese-Oxygen Intermediates in O-O Bond Activation and Hydrogen-Atom Transfer Reactions. Acc Chem Res 2017, 50 (11), 2706-2717.
Massie, A. A.; Denler, M. C.; Cardoso, L. T.; Walker, A. N.; Hossain, M. K.; Day, V. W.; Nordlander, E.; Jackson, T. A., Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes. Angewandte Chemie International Edition 2017, 56 (15), 4178-4182.
Leto, D. F.; Massie, A. A.; Rice, D. B.; Jackson, T. A. Spectroscopic and Computational Investigations of a Mononuclear Manganese(IV)-Oxo Complex Reveal Electronic Structure Contributions to Reactivity. J Am Chem Soc 2016, 138, 15413-15424.
Rice, D. B.; Wijeratne, G. B.; Burr, A. D.; Parham, J. D.; Day, V. W.; Jackson, T. A. Steric and Electronic Influence on Proton-Coupled Electron-Transfer Reactivity of a Mononuclear Mn(III)-Hydroxo Complex. Inorg Chem 2016, 55, 8110-8120.
Lohrman, J.; Telikepalli, H.; Johnson, T. S.; Jackson, T. A.; Day, V. W.; Bowman-James, K. Pyrazinetetracarboxamide: A Duplex Ligand for Palladium(II). Inorg. Chem. 2016, 55, 5098-5100.
Leto, D. F.; Massie, A. A.; Colmer, H. E.; Jackson, T. A. X-Band Electron Paramagnetic Resonance Comparison of Mononuclear Mn(IV)-oxo and Mn(IV)-hydroxo Complexes and Quantum Chemical Investigation of Mn(IV) Zero-Field Splitting. Inorg Chem 2016, 55, 3272-3282.
Colmer, H. E.; Howcroft, A. W.; Jackson, T. A. Formation, Characterization, and O-O Bond Activation of a Peroxomanganese(III) Complex Supported by a Cross-Clamped Cyclam Ligand. Inorg Chem 2016, 55, 2055-2069.
Colmer, H. E.; Margarit, C. G.; Smith, J. M.; Jackson, T. A.; Telser, J. Spectroscopic and Computational Investigation of Low-Spin MnIII Bis(scorpionate) Complexes. European Journal of Inorganic Chemistry 2016, 2016, 2413-2423.
Wijeratne. G. B.; Day. V. W.; Jackson, T. A.; "O-H bond oxidation by a monomeric Mn^III-OMe complex" Dalton Trans., 2015, 44, 3295-3306.
Wijeratne, G. B.; Zolnhofer, E. M.; Fortier, S.; Grant, L. N.; Carroll, P. J.; Chen. C.-H.; Meyer, K.; Krzystek, J.; Ozarowski, A.; Jackson, T. A.; Mindiola. D. J., Telser, J.; "Electronic Structure and Reactivity of a Well-Defined Mononuclear Complex of Ti(II)" Inorg. Chem., 2015, 54, 10380-10397.
Kumar, M.; Chaudhari, R. V.; Subramaniam, B.; Jackson, T. A. Importance of Long-Range Noncovalent Interactions in the Regioselectivity of Rhodium-Xantphos-Catalyzed Hydroformylation. Organometallics 2015, 34, 1062-1073.
Colmer, H. E.; Geiger, R. A.; Leto, D. F.; Wijeratne, G. B.; Day, V. W.; Jackson, T. A.; "Geometric and electronic structure of a peroxomanganese(III) complex supported by a scorpionate ligand" Dalton Trans., 2014, 43, 17949-17963.
Kumar, M.; Chaudhari, R. V.; Subramaniam, B.; Jackson, T. A., "Ligand Effects on the Regioselectivity of Rhodium-Catalyzed Hydroformylation: Density Functional Calculations Illuminate the Role of Long-Range Noncovalent Interactions" Organometallics, 2014, 33, 4183-4191.
Wijeratne, G. B.; Corzine, B.; Day, V. W.; Jackson, T. A.; "Saturation Kinetics in Phenolic O–H Bond Oxidation by a Mononuclear Mn(III)–OH Complex Derived from Dioxygen" Inorg. Chem., 2014, 53, 7622-7634.
Leto, D. F.; Jackson, T. A.; "Mn K-Edge X-ray Absorption Studies of Oxo- and Hydroxo-manganese(IV) Complexes: Experimental and Theoretical Insights into Pre-Edge Properties" Inorg. Chem., 2014, 53, 6179–6194.
Begum, R. A.; Day, V. W.; Kumar, M.; Gonzalez, J.; Jackson, T. A.; Bowman-James, K., "M⋯H–C interaction – Agostic or not: A comparison of phenyl- versus pyridyl-bridged transition metal dimers" Inorg. Chim. Acta, 2014, 417, 287-293.
Ching, H. Y. V.; Anxolabéhère-Mallart, E.; Colmer, H. E.; Costentin, C.; Dorlet, P.; Jackson, T. A.; Policar, C.; Robert, M; "Electrochemical formation and reactivity of a manganese peroxo complex: acid driven H₂O₂ generation vs. O–O bond cleavage" Chem. Sci, 2014, 5, 2304-2310.
Leto, D. F.; Jackson, T. A.; "Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes" J. Biol. Inorg. Chem., 2014, 19, 1-15.
Wolk, A. B.; Leavitt, C. M.; Fournier, J. A.; Kamrath, M. Z.; Wijeratne, G. B.; Jackson, T. A.; Johnson, M. A., "Isolation and characterization of a peroxo manganese (III) dioxygen reaction intermediate using cryogenic ion vibrational predissociation spectroscopy" International Journal of Mass Spectrometry, 2013, 354-355, 33-38.
Forshaw, A. P.; Smith, J. M.; Ozarowski, A.; Krzystek, J.; Smirnov, D.; Zvyagin, S. A.; Harris, T. D.; Karunadasa, H. I.; Zadrozny, J. M.; Schnegg, A.; Holldack, K.; Jackson, T. A.; Alamiri, A.; Barnes, D. M.; Telser, J., "Low-Spin Hexacoordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes" Inorg. Chem., 2013, 52, 144-159.
Leto, D. F.; Chattopadhyay, S.; Day, V. W.,; Jackson, T. A.; "Reaction landscape of a pentadentate N5-ligated Mn^II complex with O₂^.-and H₂O₂ includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)-dimanganese(III,IV) species" Dalton Trans., 2013, 42, 13014-13025.
Krause, M. E.; Glass, A. M.; Jackson, T. A.; Laurence, J. S. Embedding the Ni-SOD Mimetic Ni-NCC within a Polypeptide Sequence Alters the Specificity of the Reaction Pathway. Inorg. Chem. 2013, 52, 77-83.
Leto, D. F.; Ingram, R.; Day, V. W.; Jackson, T. A.; "Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex " Chem. Commun., 2013, 49, 5378-5380.
El Ghachtouli, S.; Ching, H. Y. V.; Lassalle-Kaiser, B.; Guillot, R.; Leto, D. F.; Chattopadhyay, S.; Jackson, T. A.; Dorlet, P.; Anxolabéhère-Mallart, E.; "Electrochemical formation of Mn^III-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands" Chem. Commun., 2013, 49, 5696-5698.
Jackson, T. A.; Krzystek, J.; Ozarowski, A.; Wijeratne, G. B.; Wicker, B. F.; Mindiola, D. J.; Telser, J. "Vanadocene de Novo: Spectroscopic and Computational Analysis of Bis(eta(5)-cyclopentadienyl)vanadium(II)" Organometallics, 2012, 31, 8265-8274.
Glass, A. M.; Krause, M. E.; Laurence, J. S.; Jackson, T. A. "Controlling the Chiral Inversion Reaction of the Metallopeptide Ni-Asparagine-Cysteine-Cysteine with Dioxygen" Inorg. Chem., 2012, 51, 10055-10063.
Bane, K.; Geiger, R. A.; Chabolla, S. A.; Jackson, T. A. "Determination of zero-field splitting parameters for a MnIV center using variable-temperature, variable-field magnetic circular dichroism spectroscopy: Comparison to electron paramagnetic resonance spectroscopy" Inorg. Chim. Acta, 2012, 380, 135 - 140.
Geiger, R. A.; Wijeratne, G.; Day, V. W.; Jackson, T. A. "Steric and Electronic Influences on the Structures of Peroxomanganese(III) Complexes Supported by Tetradentate Ligands" Eur. J. Inorg. Chem. 2012, 10, 1598-1608.
Geiger, R. A.; Leto, D. F.; Chattopadhyay, S.; Dorlet, P.; Anxolabéhère-Mallart, E.; Jackson, T. A. "Geometric and Electronic Structures of Peroxomanganese(III) Complexes Supported by Pentadentate Amino-Pyridine and -Imidazole Ligands" Inorg. Chem. 2011, 50, 10190-10203.
Krause, M. E.; Glass, A. M.; Jackson, T. A.; Laurence, J. S. "MAPping the Chiral Inversion and Structural Transformation of a Metal-Tripeptide Complex Having Ni-Superoxide Dismutase Activity" Inorg. Chem. 2011, 50, 2479-2487.
Geiger, R. A.; Chattopadhyay, S.; Day, V. W.; Jackson, T. A. "Nucleophilic reactivity of a series of peroxomanganese(III) complexes supported by tetradentate aminopyridyl ligands" Dalton Trans. 2011, 40, 1707 – 1715.
Shi, S.; Wang, Y.; Xu, A.; Wang, H.; Zhu, D.; Roy, S. B.; Jackson, T. A.; Busch, D. H.; Yin, G. "Distinct Reactivity Differences of Metal Oxo and Its Corresponding Hydroxo Moieties in Oxidations: Implications from a Manganese(IV) Complex Having Dihydroxide Ligand" Angew. Chemie-Intl. Ed. 2011, 50, 7321-7324.
Chattopadhyay, C.; Geiger, R. A.; Yin, G.; Busch, D. H.; Jackson, T. A. "Oxo- and Hydroxomanganese(IV) Adducts: A Comparative Spectroscopic and Computational Study" Inorg. Chem. 2010, 49, 7530 – 7535.
Geiger, R. A.; Chattopadhyay, S.; Day, V. W.; Jackson, T. A. "A Series of Peroxomanganese(III) Complexes Supported by Tetradentate Aminopyridyl Ligands: Detailed Spectroscopic and Computational Studies" J. Am. Chem. Soc. 2010, 132, 2821 – 2831.
Krause, M. E.; Glass, A. M.; Jackson, T. A.; Laurence, J. S. "Novel Tripeptide Model of Nickel Superoxide Dismutase" Inorg. Chem. 2010, 49, 362 – 364.

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