Publications

45. Parham, J. D.; Wijeratne, G. B.; Mayfield, J. R.; Jackson, T. A., Steric control of dixoygen activation pathways for MnII complexes supported by pentadentate, amide-containing ligands Dalton Transactions 2019, 48 (15), 13034-13045.

44. Rice, D. B.; Massie, A. A.; Jackson, T. A., Experimental and Multireference ab Initio Investigations of Hydrogen-Atom-Transfer Reactivity of a Mononuclear MnIV-oxo Complex Inorganic Chemistry 2019, 58 (20), 13902-13916.

43. Denler, M. C.; Massie, A. A.; Singh, R.; Stewart-Jones, E.; Sinha, A.; Day, V. W.; Nordlander, E.; Jackson, T. A., MnIV-Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for MnIV-oxo than FeIV-oxo species Dalton Transactions 2019, 48 (15), 5007-5021.

42. Rice, D. B.; Munasinghe, A.; Grotemeyer, E. N.; Burr, A. D.; Day, V. W.; Jackson, T. A., Structure and Reactivity of (μ-Oxo)dimanganese(III,III) and Mononuclear Hydroxomanganese(III) Adducts Supported by Derivatives of an Amide-Containing Pentadentate Ligand Inorganic Chemistry 2019, 58 (1), 622-636.

41. Lee, Y.; Jackson, T. A., Ligand Influence on Structural Properties and Reactivity of Bis(μ-oxo)dimanganese(III,IV) Species and Comparison of Reactivity with Terminal MnIV-oxo Complexes Chemistry Select 2018, 3 (47), 13507-13516.

40. Denler, M. C.; Wijeratne, G. B.; Rice, D. B.; Colmer, H. E.; Day, V. W.; Jackson, T. A., MnIII-Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity Dalton Transactions 2018, 47 (38), 13442-13458.

39. Massie, A. A.; Sinha, A.; Parham, J. D.; Nordlander, E.; Jackson, T. A., Relationship between Hydrogen-Atom Transfer Driving Force and Reaction Rates for an Oxomanganese(IV) Adduct Inorganic Chemistry 2018, 57 (14), 8253-8263.

38. Rice, D. B.; Jones, S. D.; Douglas, J. T.; Jackson, T. A., NMR Studies of a MnIII-hydroxo Adduct Reveal an Equilibrium between MnIII-hydroxo and μ-Oxodimanganese(III,III) Species Inorganic Chemistry 2018, 57 (13), 7825-7837.

37. Parham, J. D.; Wijeratne, G. B.; Rice, D. B.; Jackson, T. A., Spectroscopic and Structural Characterization of Mn(III)-Alkylperoxo Complexes Supported by Pentadentate Amide-Containing Ligands. Inorganic Chemistry 2018, 57 (5), 2489-2502.

36. Rice, D. B.; Wijeratne, G. B.; Jackson, T. A., Mn K-edge X-ray absorption studies of mononuclear Mn(III)-hydroxo complexes. J Biol Inorg Chem 2017, 22 (8), 1281-1293.

35. Rice, D. B.; Massie, A. A.; Jackson, T. A., Manganese-Oxygen Intermediates in O-O Bond Activation and Hydrogen-Atom Transfer Reactions. Acc Chem Res 2017, 50 (11), 2706-2717.

34. Massie, A. A.; Denler, M. C.; Cardoso, L. T.; Walker, A. N.; Hossain, M. K.; Day, V. W.; Nordlander, E.; Jackson, T. A., Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes. Angewandte Chemie International Edition 2017, 56 (15), 4178-4182.

33. Leto, D. F.; Massie, A. A.; Rice, D. B.; Jackson, T. A. Spectroscopic and Computational Investigations of a Mononuclear Manganese(IV)-Oxo Complex Reveal Electronic Structure Contributions to Reactivity. J Am Chem Soc 2016, 138, 15413-15424.

32. Rice, D. B.; Wijeratne, G. B.; Burr, A. D.; Parham, J. D.; Day, V. W.; Jackson, T. A. Steric and Electronic Influence on Proton-Coupled Electron-Transfer Reactivity of a Mononuclear Mn(III)-Hydroxo Complex. Inorg Chem 2016, 55, 8110-8120.

31. Lohrman, J.; Telikepalli, H.; Johnson, T. S.; Jackson, T. A.; Day, V. W.; Bowman-James, K. Pyrazinetetracarboxamide: A Duplex Ligand for Palladium(II). Inorg. Chem. 2016, 55, 5098-5100.

30. Leto, D. F.; Massie, A. A.; Colmer, H. E.; Jackson, T. A. X-Band Electron Paramagnetic Resonance Comparison of Mononuclear Mn(IV)-oxo and Mn(IV)-hydroxo Complexes and Quantum Chemical Investigation of Mn(IV) Zero-Field Splitting. Inorg Chem 2016, 55, 3272-3282.

29. Colmer, H. E.; Howcroft, A. W.; Jackson, T. A. Formation, Characterization, and O-O Bond Activation of a Peroxomanganese(III) Complex Supported by a Cross-Clamped Cyclam Ligand. Inorg Chem 2016, 55, 2055-2069.

28. Colmer, H. E.; Margarit, C. G.; Smith, J. M.; Jackson, T. A.; Telser, J. Spectroscopic and Computational Investigation of Low-Spin MnIII Bis(scorpionate) Complexes. European Journal of Inorganic Chemistry 2016, 2016, 2413-2423.

27. Wijeratne. G. B.; Day. V. W.; Jackson, T. A.; "O-H bond oxidation by a monomeric Mn^III-OMe complex" Dalton Trans., 2015, 44, 3295-3306.

26. Wijeratne, G. B.; Zolnhofer, E. M.; Fortier, S.; Grant, L. N.; Carroll, P. J.; Chen. C.-H.; Meyer, K.; Krzystek, J.; Ozarowski, A.; Jackson, T. A.; Mindiola. D. J., Telser, J.; "Electronic Structure and Reactivity of a Well-Defined Mononuclear Complex of Ti(II)" Inorg. Chem., 2015, 54, 10380-10397.

25. Kumar, M.; Chaudhari, R. V.; Subramaniam, B.; Jackson, T. A. Importance of Long-Range Noncovalent Interactions in the Regioselectivity of Rhodium-Xantphos-Catalyzed Hydroformylation. Organometallics 2015, 34, 1062-1073.

24. Colmer, H. E.; Geiger, R. A.; Leto, D. F.; Wijeratne, G. B.; Day, V. W.; Jackson, T. A.; "Geometric and electronic structure of a peroxomanganese(III) complex supported by a scorpionate ligand" Dalton Trans., 2014, 43, 17949-17963.

23. Kumar, M.; Chaudhari, R. V.; Subramaniam, B.; Jackson, T. A., "Ligand Effects on the Regioselectivity of Rhodium-Catalyzed Hydroformylation: Density Functional Calculations Illuminate the Role of Long-Range Noncovalent Interactions" Organometallics, 2014, 33, 4183-4191.

22. Wijeratne, G. B.; Corzine, B.; Day, V. W.; Jackson, T. A.; "Saturation Kinetics in Phenolic O–H Bond Oxidation by a Mononuclear Mn(III)–OH Complex Derived from Dioxygen" Inorg. Chem., 2014, 53, 7622-7634.

21. Leto, D. F.; Jackson, T. A.; "Mn K-Edge X-ray Absorption Studies of Oxo- and Hydroxo-manganese(IV) Complexes: Experimental and Theoretical Insights into Pre-Edge Properties" Inorg. Chem., 2014, 53, 6179–6194.

20. Begum, R. A.; Day, V. W.; Kumar, M.; Gonzalez, J.; Jackson, T. A.; Bowman-James, K., "M⋯H–C interaction – Agostic or not: A comparison of phenyl- versus pyridyl-bridged transition metal dimers" Inorg. Chim. Acta, 2014, 417, 287-293.

19. Ching, H. Y. V.; Anxolabéhère-Mallart, E.; Colmer, H. E.; Costentin, C.; Dorlet, P.; Jackson, T. A.; Policar, C.; Robert, M; "Electrochemical formation and reactivity of a manganese peroxo complex: acid driven H₂O₂ generation vs. O–O bond cleavage" Chem. Sci, 2014, 5, 2304-2310.

18. Leto, D. F.; Jackson, T. A.; "Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes" J. Biol. Inorg. Chem., 2014, 19, 1-15.

17. Wolk, A. B.; Leavitt, C. M.; Fournier, J. A.; Kamrath, M. Z.; Wijeratne, G. B.; Jackson, T. A.; Johnson, M. A., "Isolation and characterization of a peroxo manganese (III) dioxygen reaction intermediate using cryogenic ion vibrational predissociation spectroscopy" International Journal of Mass Spectrometry, 2013, 354-355, 33-38.

16. Forshaw, A. P.; Smith, J. M.; Ozarowski, A.; Krzystek, J.; Smirnov, D.; Zvyagin, S. A.; Harris, T. D.; Karunadasa, H. I.; Zadrozny, J. M.; Schnegg, A.; Holldack, K.; Jackson, T. A.; Alamiri, A.; Barnes, D. M.; Telser, J., "Low-Spin Hexacoordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes" Inorg. Chem., 2013, 52, 144-159.

15. Leto, D. F.; Chattopadhyay, S.; Day, V. W.,; Jackson, T. A.; "Reaction landscape of a pentadentate N5-ligated Mn^II complex with O₂^.- and H₂O₂ includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)-dimanganese(III,IV) species" Dalton Trans., 2013, 42, 13014-13025.

14. Krause, M. E.; Glass, A. M.; Jackson, T. A.; Laurence, J. S. Embedding the Ni-SOD Mimetic Ni-NCC within a Polypeptide Sequence Alters the Specificity of the Reaction Pathway. Inorg. Chem. 2013, 52, 77-83.

13. Leto, D. F.; Ingram, R.; Day, V. W.; Jackson, T. A.; "Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex " Chem. Commun., 2013, 49, 5378-5380.

12. El Ghachtouli, S.; Ching, H. Y. V.; Lassalle-Kaiser, B.; Guillot, R.; Leto, D. F.; Chattopadhyay, S.; Jackson, T. A.; Dorlet, P.; Anxolabéhère-Mallart, E.; "Electrochemical formation of Mn^III-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands" Chem. Commun., 2013, 49, 5696-5698.

11. Jackson, T. A.; Krzystek, J.; Ozarowski, A.; Wijeratne, G. B.; Wicker, B. F.; Mindiola, D. J.; Telser, J. "Vanadocene de Novo: Spectroscopic and Computational Analysis of Bis(eta(5)-cyclopentadienyl)vanadium(II)" Organometallics, 2012, 31, 8265-8274.

10. Glass, A. M.; Krause, M. E.; Laurence, J. S.; Jackson, T. A. "Controlling the Chiral Inversion Reaction of the Metallopeptide Ni-Asparagine-Cysteine-Cysteine with Dioxygen" Inorg. Chem., 2012, 51, 10055-10063.

9. Bane, K.; Geiger, R. A.; Chabolla, S. A.; Jackson, T. A. "Determination of zero-field splitting parameters for a MnIV center using variable-temperature, variable-field magnetic circular dichroism spectroscopy: Comparison to electron paramagnetic resonance spectroscopy" Inorg. Chim. Acta, 2012, 380, 135 - 140.

8. Geiger, R. A.; Wijeratne, G.; Day, V. W.; Jackson, T. A. "Steric and Electronic Influences on the Structures of Peroxomanganese(III) Complexes Supported by Tetradentate Ligands" Eur. J. Inorg. Chem. 2012, 10, 1598-1608.

7. Geiger, R. A.; Leto, D. F.; Chattopadhyay, S.; Dorlet, P.; Anxolabéhère-Mallart, E.; Jackson, T. A. "Geometric and Electronic Structures of Peroxomanganese(III) Complexes Supported by Pentadentate Amino-Pyridine and -Imidazole Ligands" Inorg. Chem. 2011, 50, 10190-10203.

6. Krause, M. E.; Glass, A. M.; Jackson, T. A.; Laurence, J. S. "MAPping the Chiral Inversion and Structural Transformation of a Metal-Tripeptide Complex Having Ni-Superoxide Dismutase Activity" Inorg. Chem. 2011, 50, 2479-2487.

5. Geiger, R. A.; Chattopadhyay, S.; Day, V. W.; Jackson, T. A. "Nucleophilic reactivity of a series of peroxomanganese(III) complexes supported by tetradentate aminopyridyl ligands" Dalton Trans. 2011, 40, 1707 – 1715.

4. Shi, S.; Wang, Y.; Xu, A.; Wang, H.; Zhu, D.; Roy, S. B.; Jackson, T. A.; Busch, D. H.; Yin, G. "Distinct Reactivity Differences of Metal Oxo and Its Corresponding Hydroxo Moieties in Oxidations: Implications from a Manganese(IV) Complex Having Dihydroxide Ligand" Angew. Chemie-Intl. Ed. 2011, 50, 7321-7324.

3. Chattopadhyay, C.; Geiger, R. A.; Yin, G.; Busch, D. H.; Jackson, T. A. "Oxo- and Hydroxomanganese(IV) Adducts: A Comparative Spectroscopic and Computational Study" Inorg. Chem. 2010, 49, 7530 – 7535.

2. Geiger, R. A.; Chattopadhyay, S.; Day, V. W.; Jackson, T. A. "A Series of Peroxomanganese(III) Complexes Supported by Tetradentate Aminopyridyl Ligands: Detailed Spectroscopic and Computational Studies" J. Am. Chem. Soc. 2010, 132, 2821 – 2831.

1. Krause, M. E.; Glass, A. M.; Jackson, T. A.; Laurence, J. S. "Novel Tripeptide Model of Nickel Superoxide Dismutase" Inorg. Chem. 2010, 49, 362 – 364.

Non-KU Publications

 

From the Lawrence Que Jr.’s Lab, University of Minnesota (Post-doctoral Fellow)

8. Wang, D.; Ray, K.; Collins, M. J.; Farquhar, E. R.; Frisch, J. R.; Gómez, L.; Jackson, T. A.; Kerscher, M.; Waleska, A.; Comba, P.; Costas, M.; Que, L., Nonheme oxoiron(iv) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity. Chem. Sci. 2013, 4, 282-291.

7. McDonald, A. R.; Bukowski, M. R.; Farquhar, E. R.; Jackson, T. A.; Koehntop, K. D.; Seo, M. S.; De Hont, R. F.; Stubna, A.; Halfen, J. A.; Münck, E.; Nam, W.; Que, L., Sulfur versus Iron Oxidation in an Iron−Thiolate Model Complex. J. Am. Chem. Soc. 2010, 132, 17118-17129.

6. Jackson, T. A.; Rohde, J.-U.; Seo, M. S.; Sastri, C. V.; DeHont, R.; Ohta, T.; Stubna, A.; Kitagawa, T.; Münck, E.; Nam, W.; Que, L., Jr., Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes. J. Am. Chem. Soc. 2008, 130 (37), 12394-12407.

5. Sastri, C. V.; Lee, J.; Oh, K.; Lee, Y. J.; Lee, J.; Jackson, T. A.; Hirao, H.; Que, L., Jr.; Shaik, S.; Nam, W., Axial Tuning of a Nonheme Iron(IV)-Oxo Unit for Hydrogen Atom Abstraction. Proc. Natl. Acad. Sci. USA 2007, 104, 19181-19186.

4. Rohde, J.-U.; Betley, T. A.; Jackson, T. A.; Saouma, C. T.; Peters, J. C.; Que, L., Jr., XAS Characterization of a Nitridoiron(IV) Complex with a Very Short Fe-N Bond. Inorg. Chem. 2007, 46, 5720-5726.

3. Klinker, E. J.; Jackson, T. A.; Jensen, M. P.; Juhasz, G.; Münck, E.; Que, L., Jr., A Tosylimido Analogue of an Oxoiron(IV) Complex. Angew. Chem. Int. Ed. 2006, 45 (44), 7394-7397.

2. Jackson, T. A.; Que, L. J., Structural and Functional Models for Oxygen-Activating Nonheme Iron Enzymes. In Concepts and Models in Bioinorganic Chemistry, Kraatz, H.-B.; Metzler-Nolte, N., Eds. Wiley-VCH: Weinheim, 2006; pp 259-285.

1. Sastri, C. V.; Park, M. J.; Ohta, T.; Jackson, T. A.; Stubna, A.; Seo, M. S.; Lee, J.; Kim, J.; Kitagawa, T.; Münck, E.; Que, L., Jr.; Nam, W., Axial Ligand Substituted Nonheme Fe^IV=O Complexes: Observation of Near-UV LMCT Bands and Fe=O Raman Vibrations. J. Am. Chem. Soc. 2005, 127 (36), 12494-12495.

From Thomas C. Brunold’s Lab, University of Wisconsin-Madison (Graduate Student)

7. Jackson, T. A.; Gutman, C. T.; Maliekal, J.; Miller, A.-F.; Brunold, T. C., Geometric and Electronic Structures of Manganese-Substituted Iron Superoxide Dismutase. Inorg. Chem. 2013, 52 (6), 3356-3367.

6. Jackson, T. A.; Karapetian, A.; Miller, A.-F.; Brunold, T. C., Probing the Geometric and Electronic Structures of the Low Temperature Azide Adduct of Oxidized Manganese Superoxide Dismutase and the Product-Inhibited Complex. Biochemistry 2005, 44, 1504-1520.

5. Jackson, T. A.; Karapetian, A.; Miller, A.-F.; Brunold, T. C., Spectroscopic and Computational Studies of the Azide-Adduct of Manganese Superoxide Dismutase: Definitive Assignment of the Ligand Responsible for the Low-Temperature Thermochromism. J. Am. Chem. Soc. 2004, 126, 12477-12491.

4. Jackson, T. A.; Brunold, T. C., Combined Spectroscopic / Computational Studies on Fe- and Mn-Dependent Superoxide Dismutases: Insights into Second-Sphere Tuning of Active-Site Properties. Acc. Chem. Res. 2004, 37 (7), 461-470.

3. Jackson, T. A.; Yikilmaz, E.; Miller, A.-F.; Brunold, T. C., Spectroscopic and Computational Study of a Non-Heme Iron {Fe-NO}⁷ System: Exploring the Geometric and Electronic Structures of the Nitrosyl Adduct of Iron Superoxide Dismutase. J. Am. Chem. Soc. 2003, 125, 8348-8363.

2. Maliekal, J.; Karapetian, A.; Vance, C.; Yikilmaz, E.; Wu, Q.; Jackson, T.; Brunold, T. C.; Spiro, T. G.; Miller, A.-F., Comparison and Contrasts between the Active Site pKs of Mn-Superoxide Dismutase and Those of Fe-Superoxide Dismutase. J. Am. Chem. Soc. 2002, 124, 15064-15075.

1. Jackson, T. A.; Xie, J.; Yikilmaz, E.; Miller, A.-F.; Brunold, T. C., Spectroscopic and Computational Studies on Iron and Manganese Superoxide Dismutases: Nature of the Chemical Events Associated with Active Site pKs. J. Am. Chem. Soc. 2002, 124, 10833-10845.